Phone number: +44 (0)121 204 3917
Email: P.vankoningsbruggen@aston.ac.uk
Profile
Dr. P.J. van Koningsbruggen is an inorganic chemist with a specialisation in the field of coordination chemistry.
Qualifications & Education
Degrees
28/10/1988: Master's degree in Chemistry
Leiden University (Leiden, the Netherlands)
15/06/1994: Ph.D. degree
Leiden University (Leiden, the Netherlands), Supervisor: Prof. dr. J. Reedijk (Leiden University, the Netherlands)
Title of Ph.D. thesis: “The structures and magnetic properties of polynuclear copper(II) coordination compounds. 1,2,4-triazoles and acylamidrazones as ligands.”
Teaching qualifications
- 15 February 2012:Postgraduate Certificate in Professional Practice in Higher Education (PGCPP)
- 16 April 2012: Fellow of the Higher Education Academy
Languages
- Dutch, English, French, German, Italian
·Academic employment
- 01/1995 – 07/1995 : Post-doctoral researcher
Johannes-Gutenberg Universität Mainz, Germany
Research group of Prof. dr. P. Gütlich
- 10/1995 – 08/1997: Post-doctoral researcher
Université de Bordeaux, France
Research group of Prof. dr. O. Kahn
- 09/1997 – 08/1998: Post-doctoral researcher
University of Utah, Salt Lake City, USA
Research group of Prof. dr. J. S. Miller
- 10/1998 – 02/2000: Research collaborator
Johannes-Gutenberg Universität Mainz, Germany
Research group of Prof. dr. P. Gütlich
- 03/2000 - 12/2003: Lecturer
Johannes-Gutenberg Universität Mainz, Germany
- 01/2004 - 2010: Assistant Professor (Rosalind Franklin Fellow)
University of Groningen, Groningen, The Netherlands
- Since June 2010 Lecturer in Inorganic Chemistry, Aston University
Research visits (selection)
- 09/1987 – 07/1988: Université de Paris Sud, Orsay, France
Research group of Prof. dr. O. Kahn
- 16/07 – 20/07/1990: Université de Strasbourg, Strasbourg, France
Research group of Dr. M. Drillon
- 04/1992 – 07/1992: Università di Firenze, Florence, Italy
Research group of Prof. dr. D. Gatteschi
- 17/10 – 21/10/1994: Johannes-Gutenberg Universität Mainz, Germany
Research group of Prof. dr. P. Gütlich
- 27/06 – 02/07/1996: Memorial University, Newfoundland, Canada
Research group of Prof. dr. L. K. Thompson
- 14/10 – 25/10/1996: Johannes-Gutenberg Universität Mainz, Germany
Research group of Prof. dr. P. Gütlich
- 12/01 – 13/01/1999: Université de Strasbourg, France
Research group of Prof. dr. J.-M. Lehn
- 20/05 – 21/05/1999: Ecole Normale Supérieure de Lyon, Lyon, France
Research group of Prof. dr. A. Collet
- 11/01 – 04/02/2002: Technische Universität Wien, Vienna, Austria
- 08/03 – 08/04/2002 Research group of Prof. dr. W. Linert
- 12/08 – 18/08/2007: University of Otago, Dunedin, New Zealand
- 18/08 – 22/08/2008 Guest lecturer, Research group of Prof. dr. S. Brooker
Research Interests
Dr. P.J. van Koningsbruggen is an experimental inorganic chemist with a specialisation in the field of coordination chemistry. Since 1985 I have been focusing on various aspects of compounds of first-row transition metal ions (Mn, Fe, Ni, Co, Cu, Zn). In particular, the relation between synthetic procedures, structural features of the compounds and their physical (e.g. magnetic and electronic) properties has attracted my attention. In my research I have used a strategic and systematic approach to the design and obtaining of various types of functional materials and I have found this to be extremely worthwhile in unravelling structure-property relationships. I am convinced that the thus obtained knowledge is an essential pre-requisite for the on-going design and obtaining of materials with pre-determined and tuneable functional magnetic, electronic and/or optical properties.
The synthetic approach that I use takes advantage of building blocks (metal fragments, anions, ligands etc.) which are assembled using tools from coordination chemistry (stereochemical preferences of the metal ion, coordination geometry etc.), as well as crystal packing efficiency considerations (stacking-, hydrogen bonding and van der Waals interactions etc.). Insight in these parameters is the key to understanding and tuning the physical behaviour and/or reactivity of these transition metal compounds. In addition, the versatility of organic synthesis and the possibility of associating organic and inorganic components on the molecular scale make it possible to propose the additional challenge of engineering multi-property materials which may display synergy between a combination of physical properties.
Research Topics
· Magnetic materials
· Fe(II)-based switchable molecular compounds
· Fe(III)-based switchable molecular compounds
· Photomagnetic systems
· Catalysis
Teaching Activities
My teaching activities involve delivering modules in General and Introductory Chemistry, Inorganic Chemistry, Coordination Chemistry, Organometallic Chemistry, Physical and Analytical Chemistry and Catalysis to all the chemistry, chemical Engineering and CEAC programmes. This encompasses lectures, tutorials, supervision of experimental research projects and literature projects, and inorganic chemistry laboratory classes.
Modules
CH1111 – General and Introductory Chemistry
CH2126 – Inorganic Chemistry – Metals – Coordination Chemistry
CH3115 / CH4115 / CH3156 – Advanced Inorganic Chemistry – Organometallic Chemistry
CH3008 – Physical and Analytical Chemistry III
CH3010 – Catalysis
CE1007 – Tutorial group / Health, Safety and the Environment project
CH3117 / CH3100 – Literature Research Project
CE4005 – Chemical Engineering Master’s student research project
Membership of Professional Bodies
- Member of the Royal Society of Chemistry
· Fellow of the Higher Education Academy
Publications
1 "Chemistry and physics of molecular based ferromagnets."
Y. Journaux, P. J. van Koningsbruggen, F. Lloret, K. Nakatani, Y. Pei, O. Kahn
and J. P. Renard
Journal de Physique, 1988, C8-851, 49.
2 "Magnetism of ACu(II) bimetallic chain compounds (A = Fe, Co, Ni): One- and
three dimensional behaviors."
P. J. van Koningsbruggen, O. Kahn, K. Nakatani, Y. Pei, J. P. Renard, M. Drillon
and P. Legoll
Inorg. Chem., 1990, 29, 3325.
3 "Structure of trans-bis[4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole-N1,N'[diaqua-
manganese(II) dibromide."
C. Faulmann, P. J. van Koningsbruggen, R. A. G. de Graaff, J. G. Haasnoot and J.
Reedijk
Acta Crystallogr., 1990, C46, 2357.
4 "Structure of bis[m-4-amino-3,5-bis(aminomethyl)-1,2,4-triazole-N',N1,N2,N"]bis
[diaquacopper(II)] bis(sulfate) tetrahydrate."
P. J. van Koningsbruggen, J. G. Haasnoot, R. A. G. de Graaff, J. Reedijk and
S. Slingerland
Acta Crystallogr., 1992, C48, 1923.
5 "A novel type of twisted antiparallel double-chain structure with stacking
between the two strands. Structure, synthesis and magnetic properties of
[{[Cu3L2(dien)(H2O)2] 3H2O} ¥ ] [L = 1H-1,2,4-triazole-3,5-dicarboxylate(3-),
dien = 3-azapentane-1,5-diamine]."
P. J. van Koningsbruggen, J. W. van Hal, E. Müller, R. A. G. de Graaff, J. G.
Haasnoot and J. Reedijk
J. Chem. Soc., Dalton Trans., 1993, 1371.
6 "A novel tetranuclear copper(II) cluster containing twisted hydrazide bridges.
X-ray crystal structure and magnetic properties of tetrakis[(N,N'-imidopicolinyl-
oxamylhydrazine)-copper(II)] tetranitrate octahydrate."
P. J. van Koningsbruggen, E. Müller, J. G. Haasnoot and J. Reedijk
Inorg. Chim. Acta, 1993, 208, 37.
7 "The first dinuclear m-hexafluorosilicato copper(II) compound. Synthesis and
crystal structure of (m-hexafluorosilicato-kF:kF')-bis[aqua(N3-salicyloylpyridine-
2-carboxamidrazonato-k 3 N',N2,O)copper(II)]dihydrate."
P. J. van Koningsbruggen, J. G. Haasnoot, R. A. G. de Graaff and J. Reedijk
J. Chem. Soc., Dalton Trans., 1993, 483.
8 "Synthesis, crystal structure and magnetic properties of a linear trinuclear
copper(II) compound with chloride and 4-amino-3,5-bis(hydroxymethyl)-1,2,4-
triazole as bridging ligands."
P. J. van Koningsbruggen, J. W. van Hal, R. A. G. de Graaff, J. G. Haasnoot and
J. Reedijk
J. Chem., Soc., Dalton Trans., 1993, 2163.
9 "Synthesis, characterization, crystal structures and magnetic properties of di- and
Polynuclear bis(m-3-pyridin-2-yl-1,2,4-triazolato)copper(II) compounds
containing N-methylimidazole, pyrazole or 4,4'-bipyridine as co-ligands."
P. M. Slangen, P. J. van Koningsbruggen, J. G. Haasnoot, J. Jansen, S. Gorter,
J. Reedijk, H. Kooijman, W. J. J. Smeets and A. L. Spek
Inorg. Chim. Acta, 1993, 212, 289.
10 "Synthesis, crystal structure and magnetic properties of [Cu6(tidah)2Cl10(H2O)4]-
(H2O)6, a unique imidazolato and chloro-bridged hexanuclear copper(II)
compound."
G. J. A. A. Koolhaas, W. L. Driessen, P. J. van Koningsbruggen, J. Reedijk and
A. L. Spek
J. Chem. Soc., Dalton Trans., 1993, 3803.
11 "Isotropic magnetic exchange interaction through double m-N1,N2-1,2,4-
triazolato bridges: X-ray crystal structure, magnetic properties and EPR study
of [bis(m-3-pyridin-2-yl-1,2,4-triazolato-N',N1,N2)-(sulfato-O)aqua-
copper(II)diaquacopper(II)] trihydrate."
P. M. Slangen, P. J. van Koningsbruggen, K. Goubitz, J. G. Haasnoot and J.
Reedijk
Inorg. Chem., 1994, 33, 1121.
12 "The structures and magnetic properties of polynuclear copper(II) coordination
compounds. 1,2,4-triazoles and acylamidrazones as ligands."
P. J. van Koningsbruggen
Recl. Trav. Chim. Pays-Bas, 1994, 113, 416.
13 "Syntheses, spectroscopic and magnetic properties and X-ray crystal structure of
two dinuclear copper(II) compounds with the ligand N3-salicyloylpyridine-2-
carboxamidrazonato."
P. J. van Koningsbruggen, J. G. Haasnoot, R. A. G. de Graaff and J. Reedijk
Inorg. Chim. Acta., 1995, 234, 87.
14 "Isotropic and anisotropic magnetic exchange interaction through m-N(1),N(2)-
1,2,4-triazole and m-sulfato bridges: X-ray crystal structure, magnetic properties
and single crystal EPR study of [{(m-4-amino-3,5-bis(pyridin-2-yl)-1,2,4-
triazole-N',N1,N2,N")(m-sulfato-O,O')}{(sulfato-O)(aqua)copper(II)}
{(triaqua)copper(II)'}] monohydrate."
P. J. van Koningsbruggen, D. Gatteschi, R. A. G. de Graaff, J. G. Haasnoot,
J. Reedijk and C. Zanchini
Inorg. Chem., 1995, 34, 5175.
15 "Magnetic and spectroscopic properties of a series of linear homo- and
heterotrinuclear clusters with asymmetric 3,4-disubstituted 1,2,4-triazoles as
ligands."
P. J. van Koningsbruggen, J. G. Haasnoot, W. Vreugdenhil, J. Reedijk and O.
Kahn
Inorg. Chim. Acta, 1995, 239, 5.
16 "Novel hybrid spin systems of TCNQ radical anions and abpt (= 4-amino-
3,5-bis(pyridin-2-yl)-1,2,4-triazole). Crystal structure of [Fe(abpt)2(TCNQ)2] at
298 K and 100 K, Mössbauer spectroscopy, magnetic properties and infrared
spectroscopy of the series [M(II)(abpt)2(TCNQ)2] (M = Mn, Fe, Co, Ni, Cu, Zn)."
P. J. Kunkeler, P. J. van Koningsbruggen, J. P. Cornelissen, A. M. van der Kraan,
A. L. Spek, J. G. Haasnoot and J. Reedijk
J. Am. Chem. Soc., 1996, 118, 2190.
17 "Spin transition molecular materials for display and data processing."
O. Kahn, E. Codjovi, Y. Garcia, P. J. van Koningsbruggen, R. Lapouyade and
L. Sommier
Molecule-Based Magnetic Materials, (Eds: M. M. Turnbull, T. Sugimoto, L. K.
Thompson), Symposium Series No. 644, American Chemical Society,
Washington, 1996, 298.
18 "Non-classical Fe(II) spin-crossover behaviour leading to an unprecedented
extremely large apparent thermal hysteresis of 270 K: application for displays."
Y. Garcia, P. J. van Koningsbruggen, E. Codjovi, R. Lapouyade, O. Kahn and
L. Rabardel
J. Mater. Chem., 1997, 7, 857.
19 "A mixed-valence tetranuclear copper cluster with localized valencies."
P. J. van Koningsbruggen, J. G. Haasnoot, H. Kooijman, J. Reedijk and A. L.
Spek
Inorg. Chem., 1997, 36, 2487.
20 "Non-classical Fe(II) spin-crossover behaviour in polymeric iron(II) compounds
of formula [Fe(NH2trz)3]X2·xH2O (NH2trz = 4-amino-1,2,4-triazole; X =
derivatives of naphthalene sulfonate)."
P. J. van Koningsbruggen, Y. Garcia, E. Codjovi, R. Lapouyade, O. Kahn,
L. Fournès and L. Rabardel
J. Mater. Chem., 1997, 7, 2069.
21 "Spin transition in [Fe(DPEA)(NCS)2], a compound with the new tetradentate
ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (DPEA): crystal structure,
magnetic properties and Mössbauer spectroscopy."
G. Matouzenko, A. Bousseksou, S. Lecocq, P. J. van Koningsbruggen, M. Perrin,
O. Kahn and A. Collet.
Inorg. Chem., 1997, 36, 2975.
22 "Polymorphism in spin transion systems. Crystal structure, magnetic properties
and Mössbauer spectroscopy of three polymorphic modifications of
[Fe(DPPA)(NCS)2] (DPPA = (3-aminopropyl)bis(2-pyridylmethyl)amine)."
G. Matouzenko, A. Bousseksou, S. Lecocq, P. J. van Koningsbruggen, M. Perrin,
O. Kahn and A. Collet.
Inorg. Chem., 1997, 36, 5869.
23 "Synthesis, crystal structure, EXAFS and magnetic properties of catena-
poly[m-tris(4-(2'-hydroxyethyl)-1,2,4-triazole-N1,N2) copper(II)] diperchlorate
trihydrate: relevance with the structure of the iron(II) 1,2,4-triazole spin
transition molecular materials."
Y. Garcia, P. J. van Koningsbruggen, G. Bravic,P. Guionneau, D. Chasseau,
G. L. Cascarano, J. Moscovici, K. Lambert,A. Michalowicz and O. Kahn
Inorg. Chem., 1997, 36, 6357.
24 "Synthesis, X-ray structure, spectroscopic and magnetic properties of [bis(4-
amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole-N',N1)(aqua)copper(II)]
bis(hydrogensulfate)."
P. J. van Koningsbruggen, K. Goubitz, J. G. Haasnoot and J. Reedijk
Inorg. Chim. Acta., 1998, 268, 37.
25 "Synthesis, crystal structure and magnetic properties of bis[m-bis(3-pyridin-2-
yl)-1,2,4-triazole-N',N1,N2] bis[triaqua nickel(II)] tetranitrate."
P. J. van Koningsbruggen, M. W. Gluth, V. Ksenofontov, D. Walcher,
D. Schollmeyer, G. Levchenko and P. Gütlich
Inorg. Chim. Acta, 1998, 273, 54.
26 "Spin crossover in six-coordinate [Fe(II)(L)2(NCX)2] compounds with L = DPQ =
2,3-bis-(2'-pyridyl)-quinoxaline, ABPT = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-
triazole and X = S, Se: synthesis, magnetic properties and single crystal studies."
N. Moliner, M. C. Muñoz, P. J. van Koningsbruggen and J. A. Real.
Inorg. Chim. Acta., 1998, 274, 1.
27 “Influences of temperature, pressure, and lattice solvents on the spin transition
regime of the polymeric compound [Fe(hyetrz)3]A2·3H2O (hyetrz = 4-(2´-
hydroxyethyl)-1,2,4-triazole and A¯ = 3-nitrophenylsulfonate)."
Y. Garcia, P. J. van Koningsbruggen, R. Lapouyade, L. Fournès, L. Rabardel,
O. Kahn, V. Ksenofontov, G. Levchenko and P. Gütlich.
Chem. Mater., 1998, 10, 2426.
28 "Synthesis and spin-crossover characteristics of polynuclear 4-(2´-hydroxyethyl)-
1,2,4-triazole Fe(II) molecular materials."
Y. Garcia, P. J. van Koningsbruggen, R. Lapouyade, L. Rabardel, O. Kahn,
M. Wierczorek, R. Bronisz, Z. Ciunik and M. F. Rudolf.
C. R. Acad. Sci. Paris, 1998, IIc, 523.
29 "Photo-magnetism of transition metal complexes."
P. Gütlich, Y. Garcia, P. J. van Koningsbruggen and F. Renz
Conference Contributions for Introduction to Physical Techniques in Molecular
Magnetism (IPTMM’99), Part 1. Structural and Magnetic Techniques,
May 29 - June 3, 1999, Yesa (Navarra), Spain.
Zaragossa University Press, 1999.
30 "Synthesis, structure, spectroscopy and magnetism of unique propeller-type linear
trinuclear Cu(II) complexes with in-situ prepared formamidine ligands."
G. A. van Albada, P. J. van Koningsbruggen, I. Mutikainen, U. Turpeinen and
J. Reedijk.
Eur. J. Inorg. Chem., 1999, 2269.
31 "Dimetallic complexes derived from a novel dinucleating chelating symmetric
triazole ligand; crystal structure, magnetic properties and EPR study of bis[m-3,5-
diacetylamino-1,2,4-triazolato-O’,N1,N2,O”)bis(nitrato)(aqua)copper(II)]."
S. Ferrer, P. J. van Koningsbruggen, J. G. Haasnoot, J. Reedijk, H. Kooijman,
A. L. Spek, L. Lezama, A. M. Arif and J. S. Miller
J. Chem. Soc., Dalton Trans., 1999, 4269.
32 "Spin-crossover behavior of [Fe(II)(isoxazole)6](BF4)2 - A structural study."
W. Hibbs, A. M. Arif, P. J. van Koningsbruggen and J. S. Miller
Cryst. Eng. Comm., 1999, 4.
33 "Synthesis, crystal structure, spectroscopic and magnetic properties of a novel
unprecedented three-dimensional Cu(II) coordination compound of the ligand
1,2-ethyl-bis-4-(1,2,4-triazole)."
Y. Garcia, P. J. van Koningsbruggen, H. Kooijman, A. L. Spek, J. G. Haasnoot
and O. Kahn.
Eur. J. Inorg. Chem., 2000, 307.
34 "Synthesis, crystal structure, EXAFS and magnetic properties of catena [m-
tris(1,2-bis(tetrazole-1-yl)propane-N1,N1’) iron(II)] bis(perchlorate). First crystal
structure of an Fe(II) spin-crossover chain compound."
P. J. van Koningsbruggen, Y. Garcia, O. Kahn, L. Fournès, H. Kooijman, A. L.
Spek, J. G. Haasnoot, J. Moscovici, K. Provost, A. Michalowicz, F. Renz and P.
Gütlich,
Inorg. Chem., 2000, 39, 1891.
35 "Synthesis, structure and magnetic properties of a tris-(3-(pyridin-2-yl)-
1,2,4-triazole)iron(II) spin-crossover complex."
A. F. Stassen, M. de Vos, P. J. van Koningsbruggen, F. Renz, J. Ensling,
H. Kooijman, A. L. Spek, J. G. Haasnoot, P. Gütlich and J. Reedijk
Eur. J. Inorg. Chem., 2000, 2231.
36 "A new 3-D polymeric spin transition compound:
[tris(1,4-bis(tetrazol-1-yl)butane-N1,N 1)iron(II)] bis(perchlorate)."
P. J. van Koningsbruggen, Y. Garcia, H. Kooijman, A. L. Spek, J. G. Haasnoot,
O. Kahn, J. Linares, E. Codjovi and F. Varret
J. Chem. Soc., Dalton Trans., 2001, 466.
37 "Crystal structure and physical properties of the new linear chain compound
[Cu(1,2-bis(tetrazole-1-yl)ethane)3](ClO4)2 ."
P. J. van Koningsbruggen, Y. Garcia, G. Bravic, D. Chasseau and O. Kahn
Inorg. Chim. Acta, 2001, 326, 101.
38 "Catena [m-tris(1,2-bis(tetrazol-1-yl)ethane-N4,N4')iron(II)]
bis(tetrafluoroborate): Synthesis, structure, spectroscopic and magnetic
characterisation of a chain-type coordination polymer spin-crossover
compound."
J. Schweifer, P. Weinberger, K. Mereiter, M. Boca, C. Reichl, G. Wiesinger,
G. Hilscher, P. J. van Koningsbruggen, H. Kooijman, M. Grunert and W. Linert
Inorg. Chim. Acta, 2002, 339, 297.
39 "CuII chain compound showing a ferromagnetic coupling through triple
N1,N2-1,2,4-triazole bridges."
Y. Garcia, P. J. van Koningsbruggen, G. Bravic, D. Chasseau and O. Kahn
Eur. J. Inorg. Chem., 2003, 356-362.
40 "Spin transition of 1D, 2D and 3D iron(II) complex polymers - The tug-of-war
between elastic interaction and a shock-absorber effect." (invited review)
P. J. van Koningsbruggen, M. Grunert and P. Weinberger
Monatshefte für Chemie, 2003, 134, 183.
41 "One- and two-step spin crossover behavior of [FeII(isoxazole)6]2+ and the
structure and magnetic properties of triangular
[FeIII 3O(OAc)6(isoxazole)3][ClO4]."
W. Hibbs, P. J. van Koningsbruggen, A. M. Arif, W. W. Shum and
J. S. Miller
Inorg. Chem., 2003, 42, 5645.
42 "Structure and physical properties of [m-tris(1,4-bis(tetrazol-1-yl)butane-
N4,N4’)iron(II)]bis(hexafluoro-phosphate), a new Fe(II) spin-crossover
compound with a three-dimensional threefold interlocked crystal lattice"
C. M. Grunert, J. Schweifer, P. Weinberger, W. Linert, K. Mereiter, G. Hilscher,
M. Müller, G. Wiesinger and P. J. van Koningsbruggen
Inorg. Chem., 2004, 43, 155-165.
43 "Special classes of iron(II) azole spin-crossover compounds" (invited review)
P. J. van Koningsbruggen
Topics in Current Chemistry, Volume "Spin crossover in Transition Metal
Compounds", Editors: P. Gütlich and H. A. Goodwin, 2004, 233, 123-149.
44 "Iron(III) spin crossover compounds" (invited review)
P. J. van Koningsbruggen, Y. Maeda and H. Oshio
Topics in Current Chemistry,Volume "Spin crossover in Transition Metal Compounds", Editors: P. Gütlich and H. A. Goodwin, 2004, 233, 259-324.
45 "Recent advances in spin-crossover research"
P. Gütlich, P. J. van Koningsbruggen and F. Renz
Structure and Bonding, 2004, 107, 27-75.
46"The influence of defects on the electron transfer and magnetic properties of RbxMn[Fe(CN)6]y .zH2O."
E. J. M. Vertelman, E. Maccallini, D. Gournis, P. Rudolf, T. Bakas, J. Luzon, R. Broer, A. Pugzlys, T. T. A. Lummen, P. H. M. van Loosdrecht and P. J. van Koningsbruggen
Chem. Mater., 2006, 18, 1951.
47 "Synthesis and magnetic properties of Fe-Mn-Cr multinuclear complexes with 4-amino-1,2,4-triazole and oxalate ligands."
I. S. Jahro, D. Onggo, A. Ismunandar, S. I. Rahayu, E. J. M. Vertelman and P.J. van Koningsbruggen
Journal of Mathematics and Natural Sciences, 2006, 11, 95-99.
48 "Copper(II) complexes with unsymmetrical pentadentate ed3a-type diamino-tricarboxylate ligands. Crystal structures, configurational analysis and DFT study of complexes."
Z. D. Matović, A. Meetsma, V. D. Miletić and P. J. van Koningsbruggen
Inorg. Chim. Acta, 2007, 360, 2420-2431.
49 "A 2D [FeII-bistetrazole] coordination polymer exhibiting spin-crossover properties."
M. Quesada, F. Prins, O. Roubeau, P. Gamez, S. J. Teat, P. J. van Koningsbruggen, J. G. Haasnoot and J. Reedijk
Inorg. Chim. Acta, 2007, 360, 3787–3796 (special issue on Molecular Magnetism).
50 "Crystal structure and magnetic behaviour of a five-coordinate iron(III) complex of pyridoxal-4-methylthiosemicarbazone."
E. W. Yemeli Tido, E. J. M. Vertelman, A. Meetsma and P. J. van Koningsbruggen
Inorg. Chim. Acta, 2007, 360, 3896–3902 (special issue on Molecular Magnetism).
51 "Study of thermal spin crossover in [Fe(II)(isoxazole)6](BF4)2 with Mössbauer spectroscopy"
A. Bhattacharjee, P. J. van Koningsbruggen, W. Hibbs, J. S. Miller and P. Gütlich
J. Phys.:Cond. Matter., 2007, 19, 406202.
52 "[Fe(μ-btzmp)2(btzmp)2](ClO4)2: a doubly-bridged 1D spin-transition bistetrazole-based polymer showing thermal hysteresis behaviour".
M. Quesada, H. Kooijman, P. Gamez, J. Sánchez Costa, P. J. van Koningsbruggen, P. Weinberger, A. L. Spek, J. G. Haasnoot and Jan Reedijk.
J. Chem. Soc., Dalton Trans., 2007, 5434 - 5440.
53 "Study of neutral Fe(III) complexes of pyridoxal-N-substituted thiosemicarbazone with desolvation induced spin-state transformation above room temperature"
E. W. Yemeli Tido, G. O. R. Alberda van Ekenstein, A. Meetsma and
P. J. van Koningsbruggen
Inorg. Chem., 2008, 47, 143.
54 "Light- and temperature-induced electron transfer in single crystals of RbMn[Fe(CN)6]·H2O."
E. J. M. Vertelman, T. T. A. Lummen, A. Meetsma, M. W. Bouwkamp, G. Molnar, P. H. M. van Loosdrecht and P. J. van Koningsbruggen
Chem. Mater., 2008, 20, 1236.
55 "Prediction of the equilibrium structures and photomagnetic properties of the Prussian Blue analogue RbMn[Fe(CN)6] by density functional theory."
J. Luzon,M. Castro, E.J.M. Vertelman, R.Y.N. Gengler, P. J. van Koningsbruggen, O. Molodtsova, M. Knupfer, P. Rudolf, P.H.M. van Loosdrecht and R. Broer
J. Phys. Chem. A, 2008, 112 (25), 5742–5748.
56 "Bulk and surface switching in Mn-Fe-based Prussian Blue Analogues"
T.T.A. Lummen, R.Y.N. Gengler, P. Rudolf, F. Lusitani, E.J.M. Vertelman, P.J. van Koningsbruggen, M. Knupfer, O. Molodtsova, J.-J. Pireaux, P.H.M. van Loosdrecht
J. Phys. Chem. C, 2008, 112, 14158.
57 "Control of photomagnetic behavior in heterobimetallic Prussian Blue analogs."
P. J. van Koningsbruggen, E. J. M. Vertelman, H. Tchouka
Abstracts of Papers, 235th ACS National Meeting, New Orleans, LA, United States, April 6-10, 2008 (2008).
58 "Mössbauer spectroscopic study of the thermal spin crossover in [Fe(II)(isoxazole)6](ClO4)2"
A. Bhattacharjee, P. J. van Koningsbruggen, J. S. Miller, Gütlich
Journal of Physics and Chemistry of Solids, 2008, 69(11), 2713-2718.
59 "Observation of a 58oC Spin Transition for Bis[hydrotris(1,2,4-triazol-1-yl)-
borate]iron(II) by Variable Temperature Infrared Spectroscopy and Magnetic Susceptibility Measurements."
P. J. van Koningsbruggen, J. S. Miller
Sol. State Sci., 2008, 10, 1804.
60 "Synthesis, structures and physical properties of double metal cyanides."
P. J. van Koningsbruggen, E. J. M. Vertelman, H. Tchouka, A. Noble
Abstracts of Papers, 237th ACS National Meeting, Salt Lake City, UT, United States, March 22 - 26, 2009 (2009).
61 "Interplay between the charge transport phenomena and the charge-transfer phase transition in RbxMn[Fe(CN)6]y.zH2O"
G. Molnár, S. Cobo, T. Mahfoud, E. J.M. Vertelman, P. J. van Koningsbruggen, P. Demont, A. Bousseksou
J.Phys. Chem. C., 2009, 113(6), 2586-2593.
62 "Valence-tautomeric RbMnFe Prussian blue analogues: composition and time stability investigation. "
L. Salmon, E. J. M. Vertelman, C. Bartual Murgui, S. Cobo, G. Molnár, P. J. van Koningsbruggen, A. Bousseksou
Eur. J. Inorg. Chem., 2009, 6, 760-768.
63 "Nickel(II) complexes of whole set of the simple ethylenediaminetetracarboxylate ligands: DFT study of complexes invoking molecular orbital and configurational analysis."
V. D. Miletic, A. Meetsma, P. J. van Koningsbruggen, Z. D. Matovic
Inorganic Chemistry Communications., 2009, 12(8), 720-723.
64 "Metal-organic-frameworks (MOF's) based on dicyanoargentate units."
P. J. van Koningsbruggen, A. Noble, A. Meetsma
Abstracts of Papers, 238th ACS National Meeting, Washington, DC, United States, August 16-20, 2009 (2009).
65 "Tuning of the charge in octahedral ferric complexes based on pyridoxal-N substituted thiosemicarbazone ligands"
E. W. Yemeli Tido, C. Faulmann, R. Roswanda, A. Meetsma, P. J. van Koningsbruggen
J. Chem. Soc., Dalton Trans., 2010, 39, 1643 – 1651.
66 "Origin of the ESR spectrum in the Prussian blue analog RbMn[Fe(CN)6]⋅H2O"
Á. Antal, A. Jánossy, L. Forró, E. J. M. Vertelman, P. J. van Koningsbruggen, P. H. M. van Loosdrecht
Phys. Rev. B, 2010, 82, 014422.
