Mass cultivation of microalgae dates back to the mid 20th Century,
from when all of the methodologies currently used can be identified,
including shallow raceways and enclosed photobioreactors9. While the
basic principles are well established, significant technological
hurdles have persistently constrained the wide scale commercial
exploitation of microalgae, except for niche markets. Thanks to recent
advances in bioprocess engineering and increased understanding of
microalgal physiology, the opportunity now exists to effectively
exploit microalgae for combined waste remediation and bioenergy
production and significant investment is being made internationally in
this arena.
There is currently much global interest and
investment in cultivating microalgae as a source of biofuels, as they
do not directly compete with food crop-based commodities and are
typically grown in non-arable land areas. Potential biofuels from
microalgae include direct combustion, pyrolysis, hydrogen, alkanes or
“green diesel”, biodiesel alcohols (ethanol) and methane. Some
microalgae species contain a much higher percentage of extractable oil
than other oil crops– in excess of 50% compared to, e.g., 25% from
rapeseed.
Methods for efficient pyrolytic conversion of
intact biomass will be developed where the biomass is to be re-used for
energy generation at the site of production (e.g. combined heat and
power applications, where microalgae bioreactors have been used to
capture flue gas CO2). This work will be carried out at EBRI
incorporating EBRI’s patented “Aston zero waste bioenergy cycle”. The
core of the downstream processing of microalgal biomass in the project
is an intermediate pyrolysis, involving converting algae into pyrolysis
liquids, pyrolysis gas and pyrolysis char with typical ratios of 20 to
30 wt % of char and 70 to 80 wt % of vapour phase. The vapour phase is
directly coupled to the gasifier which can be gasified and will produce
syngas which can be later used for hydrogen synthesis. Alternatively
the vapour phase can be condensed to pyrolysis liquids. The total
pyrolysis liquids (about 50-60% of the energy of the input material)
will be converted to biofuels in a biorefinery. Also another route is
to run the pyrolysis gases on dual fuel engines to electric power. The
pyrolysis char, as well a CO2 neutral energy resource, can be cofired,
or can be spread on the agricultural lands as a fertilizer. The Algae
photobioreactor at the EBRI is shown in the figure presented here.